(d) $F = \frac{- dU}{dx} \Rightarrow dU = - F\ dx$
$\Rightarrow U = - \int_{0}^{x}{\left( - Kx + ax^{3} \right)dx = \frac{kx^{2}}{2}} - \frac{ax^{4}}{4}$
$\therefore$ We get $U = 0$ at $x = 0$ and $x = \sqrt{2k/a}$
And also $U =$ negative for $x > \sqrt{2k/a}$
So $F = 0$ at $x = 0$
$i.e.$ slope of $U - x$ graph is zero at $x = 0$