(d) Potential energy of the particle $U = k(1 - {e^{- x}}^{2})$
Force on particle $F = \frac{- dU}{dx} = - k\lbrack - {e^{- x}}^{2} \times ( - 2x)\rbrack$
$F = - 2kx{e^{- x}}^{2} = - 2kx\left\lbrack 1 - x^{2} + \frac{x^{4}}{2!} - \ldots \right\rbrack$
For small displacement $F = - 2kx$
$\Rightarrow F \propto - x$ $i.e.$ motion is simple harmonic motion