(a) $AB = L,\ AC = \frac{L}{2};AD = l\ (say)$
Let $A$ = area of cross-section of the rod
Weight of the rod $= AL\ \rho\ g$ acting vertically downwards at $C$
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Upthrust of liquid on rod $= Al\ \sigma\ g$, acting upwards through the mid-point of $AD$
For rotational equilibrium of rod net torque about point $A$ should be zero. So
$(LA\rho\ g)\frac{L}{2}\cos\theta = (l\ A\ \sigma g)\frac{l}{2}\cos\theta\ or\frac{l^{2}}{L^{2}} = \frac{\rho}{\sigma}\ $
Or $\sin{\theta = \frac{1}{2}\sqrt{\frac{\sigma}{\rho}}}$