(b) For $\theta t$ plot, rate of cooling $= \frac{d\theta}{dt} =$ slope of the curve
At $P,\frac{d\theta}{dt} = \tan\phi_{2} = k\left( \theta_{2} - \theta_{0} \right),\ $where$\ k =$ constant
At $Q,\frac{d\theta}{dt} = \tan\phi_{1} = k\left( \theta_{1} - \theta_{0} \right) \Rightarrow \frac{\tan\phi_{2}}{\tan\phi_{1}} = \frac{\theta_{2} - \theta_{0}}{\theta_{1} - \theta_{0}}$