(a) Let $m\ gm$ of steam get condensed into water (By heat loss). This happens in following two steps.
Heat gained by water $(20℃)$ to raise it’s temperature upto $90^{o} = 22 \times 1 \times (90 - 20)$
Hence, in equilibrium heat lost = Heat gain
$\Rightarrow m \times 540 + m \times 1 \times (100 - 90) = 22 \times 1 \times (90 - 20)$
$\Rightarrow m = 2.8\ g$
The net mass of the water present in the mixture
$= 22 + 2.8 = 24.8\ g$