(a) It is given that $\frac{K_{1}}{K_{2}} = \frac{1}{3} \Rightarrow K_{1} = K$ then $K_{2} = 3K$ the temperature of the junction in contact
$\theta = \frac{K_{1}\theta_{1} + K_{2}\theta_{2}}{K_{1} + K_{2}} = \frac{1 \times 100 + 3 \times 0}{1 + 3} = \frac{100}{4} = 25℃$