(a) Temperature of interface $\theta = \frac{K_{1}\theta_{1} + K_{2}\theta_{2}}{K_{1} + K_{2}}$
[$\because\frac{K_{1}}{K_{2}} = \frac{1}{4} \Rightarrow If\ K_{1} = K\ $then$\ K_{2} = 4K$]
$\Rightarrow \theta = \frac{K \times 0 + 4K \times 100}{5K} = 80℃$