(a) Process 1 is isobaric $(p =$ constant) expansion
Hence, temperature of gas will increase
$\therefore\ \mathrm{\Delta}U_{1} =$ negative
Process 2 is an adiabatic expansion
$\therefore\ \mathrm{\Delta}U_{2} = 0$
Process 3 is an adiabatic expansion
Hence, temperature of gas will fall
$\therefore\ \ \mathrm{\Delta}U_{3} =$ constant
$\therefore\ \ \mathrm{\Delta}U_{1} > \mathrm{\Delta}U_{2} > \mathrm{\Delta}U_{3}$