(b) As is clear from figure,
Slope of curve 2 > Slope of curve 1
$(\gamma p)_{2} = (\gamma p)_{1}$
$\gamma_{2} > \gamma_{1}$
As $\gamma_{He} > \gamma O_{2}$
$\therefore$ adiabatic curve 2 corresponds to helium and adiabatic curve 1 corresponds to oxygen