(d) Here, $p = 4.5 \times 10^{5}\ Pa$,
$dV = (2.0 - 0.5)m^{3} = 1.5\ m^{3}$
$dU = ?,\ dQ = 800\ kJ = 8 \times 10^{5}\ J$
$dW = pdV = 4.5 \times 10^{5} \times 1.5 = 6.75 \times 10^{5}\ J$
$dU = dQ - dW = 8 \times 10^{5} - 6.75 \times 10^{5}$
$= 1.25 \times 10^{5}\ J$