(c) Maximum value of efficiency
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \eta = 1 - \frac{T_{2}}{T_{1}} = 1 - \frac{300}{500} = \frac{2}{5}$
As $\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \eta = \frac{W}{Q_{1}}$
$W = \eta Q_{1} = \frac{2}{5} \times 1000\ cal$
$= 400 \times 4.2\ J = 1680\ J$
As no engine can produce more than 1680 J, disigns A and B are not possible.