
(d) As initial and final states in the two processes are same. Therefore, $\mathrm{\Delta}U_{1} = \mathrm{\Delta}U_{2}$. As area under curve $a >$ area under curve $b$, therefore, $\mathrm{\Delta}W_{1} > \mathrm{\Delta}W_{2}$
As $\mathrm{\Delta}Q = \mathrm{\Delta}U + \mathrm{\Delta}W$
$\therefore\ \mathrm{\Delta}Q_{1} > \mathrm{\Delta}Q_{2}$