(a) For adiabatic process,
dQ=0
So, $dU = - \Delta W$
$\Rightarrow \ \ \ \ \ nC_{V}dT = + 146 \times 10^{3}J$
$\Rightarrow \ \ \ \ \frac{nfR}{2} \times 7 = 146 \times 10^{3}$
$\lbrack f \rightarrow Degree\ of\ freedom\rbrack$
$\Rightarrow \ \ \frac{10^{3} \times f \times 8.3 \times 7}{2} = 146 \times 10^{3}$
$f\ = 5.02 \approx 5$
So, it is a diatomic gas.