(a) From FLOT $\mathrm{\Delta}Q = \mathrm{\Delta}U + \mathrm{\Delta}W = \mathrm{\Delta}U + P\mathrm{\Delta}V$ $\Rightarrow 100 = \mathrm{\Delta}U + 50 \times (4 - 10) \Rightarrow \mathrm{\Delta}U = 400\ J$
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