
(a) $\mathrm{\Delta}W_{AB} = p\mathrm{\Delta}V = 10(2 - 1) = 10J$
$\mathrm{\Delta}W_{BC} = 0$, becuase $V$ is constant,
From first law of thermodynamics,
$\mathrm{\Delta}Q = \mathrm{\Delta}W + \mathrm{\Delta}U$
As $ABCA$ is a cyclic process, therefore,
$\mathrm{\Delta}U = 0$
$\therefore\ \mathrm{\Delta}Q = \mathrm{\Delta}W_{AB} + \mathrm{\Delta}W_{BC} + \mathrm{\Delta}W_{CA}$
$= \mathrm{\Delta}W_{AB} + \mathrm{\Delta}W_{CA}$
or $\mathrm{\Delta}W_{CA} = \mathrm{\Delta}Q - \mathrm{\Delta}W_{AB} = 5 - 10 = - 5\ J$