(a) Internal energy of an ideal gas is given by
$U = \frac{f}{2}\mu RT = \frac{f}{2}\left( \frac{N}{N_{A}} \right)RT \Rightarrow U \propto NT$
In isothermal process $T =$ constant $\Rightarrow U \propto N$
$i.e.$ internal energy increases by increasing number of molecules ($N$)