(a) $\because\theta_{1} < \theta_{2} \Rightarrow \tan\theta_{1} < \tan\theta_{2} \Rightarrow \left( \frac{V}{T} \right)_{1} < \left( \frac{V}{T} \right)_{2}$
Form $PV = \mu RT;\frac{V}{T} \propto \frac{1}{P}$
Hence $\left( \frac{1}{P} \right)_{1} < \left( \frac{1}{P} \right)_{2} \Rightarrow P_{1} > P_{2}$