(a) $22\ g\ of\ CO_{2}$ is half mole of $CO_{2}\ ie,\ n_{1} = 0.5$
16 g of $O_{2}$ is half mole of $O_{2}\ ie,\ n_{2} = 0.5\ $
$\therefore\ T = \ \frac{n_{1}T_{1} + n_{2}T_{2}}{n_{1} + n_{2}}$
= $\frac{0.5 \times (27 + 273) + 0.5(37 + 273)}{0.5 + 0.5}$
= 305 K
= 305$- 273 = 32℃$