(a) As $\theta_{2} > \theta_{1} \Rightarrow \tan\theta_{2} > \tan\theta_{1} \Rightarrow \left( \frac{T}{P} \right)_{2} > \left( \frac{T}{P} \right)_{1}$ Also from $PV = \mu RT;\frac{T}{P} \propto V \Rightarrow V_{2} > V_{1}$
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