(a) $V \propto T \Rightarrow \frac{V_{1}}{V_{2}} = \frac{T_{1}}{T_{2}} \Rightarrow \frac{200}{V_{2}} = \frac{(273 + 20)}{(273 - 20)} = \frac{293}{253}$ $\Rightarrow V_{2} = \frac{200 \times 253}{293} = 172.6ml$
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Ph.D. in Physics with 19+ years of teaching experience.