(d) Degree of freedom $f = 3$ (Translatory)+2(rotatory)+1(vibratory) = 6 $\Rightarrow \frac{C_{P}}{C_{V}} = \gamma = 1 + \frac{2}{f} = 1 + \frac{2}{6} = \frac{4}{3} = 1.33$
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Ph.D. in Physics with 19+ years of teaching experience.