(c) $\gamma_{poly} = \frac{(4 + f_{vib})}{(3 + f_{vib})}$
$f_{vib} =$ degree of freedom due to vibration $\Rightarrow \gamma_{poly} < \frac{4}{3}$
Or $\gamma_{poly} < 1.33$
Also you can remember that as the atomicity of gas increases the value of $\gamma$-decreases