(d) Equation of simple harmonic wave is
$y = A\sin{(\omega t + \varnothing)}$
Here, $y = \frac{A}{2}$
$\therefore\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ A\sin{(\omega t + \varnothing)} = \frac{A}{2}\ $
So, $\delta = \omega t + \varnothing = \frac{\pi}{6}\ \ or\ \ \ \frac{5\pi}{6}$
So, the phase difference of the two particles when they are crossing each other at $y = \frac{A}{2}$ in opposite directions are
$\delta = \delta_{1} - \delta_{2} = \frac{5\pi}{6} - \frac{\pi}{6} = \frac{2\pi}{3}$