(d) Charges on capacitors are $Q_{1} = 30 \times 2 = 60pC$ and $Q_{2} = 20 \times 3 = 60pC$ or $Q_{1} = Q_{2} = Q$ (say)
The situation is similar as the two capacitors in series are first charged with a battery of emf $50\ V$ and then disconnected
$\therefore$ when $S_{3}$ is closed $V_{1} = 30V$ and $V_{2} = 20V$