(a) During the growth of voltage in a $C - R$ circuit the voltage across a capacitor at time $t$ is given by $V = V_{0}(1 - e^{\frac{t}{CR}})$ for the given circuit as per given conduction at time $t$
$V = \frac{3}{4}$ th of the voltage applied across $C = \frac{3}{4}V_{0}$
So, $\frac{3}{4}V_{0} = V_{0}\left( 1 - e^{\frac{t}{RC}} \right) \Rightarrow e^{\frac{t}{RC}} = \frac{1}{4} \Rightarrow e^{\frac{t}{RC}} = 2^{2}$
$\Rightarrow 2RC\ln 2 = 2 \times (2.5 \times 10^{6}) \times (4 \times 10^{- 6}) \times (0.693)$
$= 13.86\ s$