(b) The three forces acting on each sphere are :
(i) Tension
(ii) Weight
(iii) Electrostatic force of repulsion
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For sphere 1
In equilibrium, from figure
$T_{1}{\cos\theta}_{1} = M_{1}g;T_{1}{\sin\theta}_{1} = F_{1}$
$\therefore\tan\theta_{1} = \frac{F_{1}}{M_{1}g}$
For sphere 2
In equilibrium, from figure
$T_{2}{\cos\theta}_{2} = M_{2}g;T_{2}{\sin\theta}_{2} = F_{2}$
$\therefore\tan\theta_{2} = \frac{F_{2}}{M_{2}g}$
Force of repulsion between two charges are same.
$\therefore F_{1} = F_{2}$
$\theta_{1} = \theta_{2}$ only if $\frac{F_{1}}{M_{1}g} = \frac{F_{2}}{M_{2}g}$
But $F_{1} = F_{2},$ then $M_{1} = M_{2}$