(c) Electric flux, $\phi = \mathbf{E.S}$
Or $\phi = ES\cos\theta$
Here, $\theta\ $is the angle between E and S. In this question$\theta = 45{^\circ}$, because S is perpendicular to surface.
$E = E_{0}$
$S = \left( \sqrt{2a} \right)(a) = \sqrt{2a^{2}}$
$\therefore\phi = \left( E_{0} \right)\left( \sqrt{2a^{2}} \right)\cos\ 45{^\circ} = E_{0}a^{2}$
∴ Correct option is (C).