(a) When key is open, charge in steady state will be $q_{1} = CE$
When key is closed, potential difference across capacitor will be
$V = \frac{2R}{R + 2R}E = \frac{2}{3}E$
Charge in steady state will be $q_{2} = \frac{2}{3}CE \Rightarrow \frac{q_{1}}{q_{2}} = \frac{3}{2}$