(a) When the two conducting spheres are connected by a conducting wire, charge will flow from one sphere (having higher potential) to other (having lower potential) till both acquire the same potential.
$E = \frac{1}{4\pi\varepsilon_{0}}.\frac{q}{r^{2}}$
So,
$\frac{E_{1}}{E_{2}} = \left( \frac{r_{2}}{r_{1}} \right)^{2} = 4:1\ $