(c) Plane conducting surfaces facing each other must have equal and opposite charge densities. Here as the plate areas are equal, $Q_{2} = - Q_{3}$.
The charge on a capacitor means the charge on the inner surface of the positive plate [Here it is $Q_{2}$]
Potential difference between the plates
$= \frac{charge}{capacitance} = \frac{Q_{2}}{C} = \frac{2Q_{2}}{2C}$
$= \frac{Q_{2} - ( - Q_{2})}{2C} = \frac{Q_{2} - Q_{3}}{2C}$