(d) For discharging of an $RC$ circuit,
$V = V_{0}e^{- t/\tau}$
So, when $V = \frac{V_{0}}{2}$
$\frac{V_{0}}{2} = V_{0}e^{- t/\tau}$
$\mathcal{l}n\frac{1}{2} = - \frac{t}{\tau} \Rightarrow \tau = \frac{1}{\mathcal{l}n2}$
From graph when $V = \frac{V_{0}}{2},t = 100s$
$\therefore\tau = \frac{100}{\mathcal{l}n2} = 144.3\ \sec$