(d) With $S_{1}$and $S_{3}$ closed, the capacitors $C_{1}$ and${\ C}_{2}$ are in series arrangement. In series arrangement potential difference developed across capacitors are in the inverse radio of their capacities. Hence,
$\frac{V_{1}^{'}}{V_{2}^{'}} = \frac{C_{2}}{V_{1}} = \frac{3pF}{3pF} = \frac{3}{2}$and
$V_{1}^{'} + V_{2}^{'} = V_{1} + V_{2} = 30 + 20 = 50V$
On simplification, we get $V_{1}^{'} = V_{1} = 30V\ and\ V_{2}^{'} = V_{2} = 20\ V$