(a) The potential due to charge $q$ at distance $r$ is given by
$V = \frac{1}{4\pi\varepsilon_{0}}\frac{q}{r}$
If $W$ be the work done in moving the charge from $A\ to\ B$ then the potential difference $(V)$ is given by
$V_{A} - V_{B} = \frac{W}{q}$
Both work (W) and charge (q) are scalar quantities hence potential difference $\left( V_{A} - V_{B} \right)$will also be a scalar quantity.
Here,
$V_{A} = V_{B} = \frac{1}{4\pi\varepsilon_{0}}\frac{\mathcal{Q}}{a/\sqrt{2}}$
Since, $\mathcal{Q}$is same for both,
$V_{A} - V_{B} = 0$
$W = 0$
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