(a) When charge $q_{3}$is at $C$, then its potential energy is
$U_{C} = \frac{1}{4\pi\varepsilon_{0}}\left( \frac{q_{1}q_{3}}{0.4} + \frac{q_{2}q_{3}}{0.5} \right)$
Where charge $q_{3}$is at $D$, then
$U_{D} = \frac{1}{4\pi\varepsilon_{0}}\left( \frac{q_{1}q_{3}}{0.4} + \frac{q_{2}q_{3}}{0.1} \right)$
Hence, change in potential energy
$\mathrm{\Delta}U = U_{D} - U_{C}$
$= \frac{1}{4\pi\varepsilon_{0}}\left( \frac{q_{2}q_{3}}{0.1} - \frac{q_{2}q_{3}}{0.5} \right)$
$but\ \ \ \ \mathrm{\Delta}U = \frac{q_{3}}{4\pi\varepsilon_{0}}k\ $
$\therefore\frac{q_{3}}{4\pi\varepsilon_{0}}k = \frac{1}{4\pi\varepsilon_{0}}\left( \frac{q_{2}q_{3}}{0.1} - \frac{q_{2}q_{3}}{0.5} \right)$
$\Longrightarrow k = q_{2}(10 - 2) = 8q_{2}$