(b) Remember mass of the metal deposited on cathode depends on the current through the voltameter and not on the current supplied by the battery. Hence by using
$m = Zit,\ $we can say$\ \frac{m_{Parallel}}{m_{Series}} = \frac{i_{Parallel}}{i_{Series}}$
$\Rightarrow m_{Parallel} = \frac{5}{2} \times 1 = 2.5\ gm.$
Hence increase in mass $= 2.5 - 1 = 1.5\ g$