(d) When one call is wrongly connected in series, the emf of cells decrease by $2\ E$, but internal resistance of cells remains the same for all the cells.
Current in the circuit is $i = \frac{(n - 2)E}{nr} \times r$
Potential difference across each cell is
$V = E - Ir = E - \frac{(n - 2)E}{nr} \times r = \frac{2E}{n}$