(a) In the steady state, no current flows through capacitor branch.
Current in the circuit
$i = \frac{net\ emf}{net\ resistance}$
$\ \ \ = \frac{2E - E}{r + 2r} = \frac{E}{3r}$
So, potential drop across capacitor
$V = ir = \frac{E}{3r} \times r = \frac{E}{3}$