(d) Since all the given forces are lying in plane, so the given loop is in equilibrium
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$F_{4}^{''} = F_{4}\cos\phi = F_{2}$
$F_{4}^{''''} = F_{4}\sin\phi = F_{3} - F_{1}$
$\Rightarrow F_{4}^{2} = F_{2}^{2} + \left( F_{3} - F_{1} \right)^{2}$
$\Rightarrow F_{4} = \sqrt{F_{2}^{2} + \left( F_{3} - F_{1} \right)^{2}}$