(d) $\frac{1}{f} = \left( \frac{n_{2}}{n_{1}} - 1 \right)\left( \frac{1}{R_{1}} - \frac{1}{R_{2}} \right)$ where $n_{2}$ and $n_{1}$ are the refractive indices of the material of the lens and of the surroundings respectively. For a double concave lens, $\left( \frac{1}{R_{1}} - \frac{1}{R_{2}} \right)$ is always negative
Hence $f$ is negative only when $n_{2} > n_{1}$