(a) Brewster discovered that when a beam of unpolarised light is reflected from a transparent medium (refractive index =$\mu$), the reflected light is completely plane polarized at a certain angle of incidence (called the angle of polarization $\theta_{p}$)
Also, $\mu = \tan\theta_{p}$
$\therefore$ Here, $\theta_{p} = \ \theta_{1} = \tan^{- 1}(1.62)$