(b) For total internal reflection to take place
$i > \ \theta c$
Taking sine on both sides, we get
$\sin i > \sin{\theta c}$
[as angle i at both face will be 45${^\circ}$]
$\Longrightarrow \frac{1}{\sqrt{2}} > \frac{1}{\mu}$
$\Longrightarrow \mu > \sqrt{2}$