(d) The phase difference $(\phi)$ between the wavelets from the top edge and the bottom edge of the slit is $\phi = \frac{2\pi}{\lambda}\ \left( d\sin\theta \right)$ where d is the slit width. The first minima of the diffraction pattern occurs at $\sin\theta = \frac{\lambda}{d},\ so\ \phi = \frac{2\pi}{\lambda}\left( d \times \frac{\lambda}{d} \right) = 2\pi$