(d) For a grating $(e + d)\sin{\theta_{n} = n\lambda}$
Where $(e + d) =$ grating element
$\sin\theta_{n} = \frac{n\lambda}{(e + d)}$
For $n = 1,\sin\theta_{1} = \frac{\lambda}{(e + d)} = \sin{32{^\circ}}$
This is more than 0.5. Now $\sin\theta_{2}$ will be more than $2 \times 0.5$, which is not possible