(d) The phase difference $(\phi)$ between the wavelets from the top edge and the bottom edge of the slit is $\phi = \frac{2\pi}{\lambda}(d\sin\theta)$ where $d$ is the slit width. The first minima of the diffraction pattern occurs at $\sin\theta = \frac{\lambda}{d}$ so $\phi = \frac{2\pi}{\lambda}\left( d \times \frac{\lambda}{d} \right) = 2\pi$