(a) Use Bragg’s $X$-ray diffraction Law
$n\lambda = 2d\sin\theta$
$\therefore\lambda = \frac{2d\sin\theta}{n}$
For longest wavelength take sin $\theta = 1$
$\therefore\lambda = \frac{2 \times 2.82\lbrack\mathring{\mathrm{A}}\rbrack}{2}\lbrack\because n = 2\ $for second order]
$= 2.82\ \mathring{\mathrm{A}}$