(b) At distance of closest approach relative velocity of two particles is $v$. Here target is considered as stationary, so $\alpha$-particle comes to rest instantaneously at distance of closest approach. Let required distance is $r,$ then from work energy-theorem.
$0 - \frac{{mv}^{2}}{2} = - \frac{1}{{4\pi\varepsilon}_{0}}\frac{Z_{e} \times Z_{e}}{r}$
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ r \propto \frac{1}{m}$
$\propto \frac{1}{v^{2}}$
$\propto {Ze}^{2}$