(b) Let ground state energy (in $eV$) be $E_{1}$
Then from the given condition
$E_{20} - E_{1} = 204eV$
Or $\frac{E_{1}}{4n^{2}} - E_{1} = 204eV$
$\Rightarrow E_{1}\left( \frac{1}{4n^{2}} - 1 \right) = 204eV$ …(i)
and $E_{2n} - E_{n} = 40.8eV$
$\Rightarrow \frac{E_{1}}{4n^{2}} - \frac{E_{1}}{n^{2}} = E_{1}\left( - \frac{3}{4n^{2}} \right) = 40.8eV$ …(ii)
From equation (i) and (ii)
$\frac{1 - \frac{1}{4n^{2}}}{\frac{3}{4n^{2}}} = 5 \Rightarrow n = 2$