(d) Helium atom has 2 electrons. When one electron is removed, the remaining atom is hydrogen like atom, whose energy in first orbit is
$E_{1} = - (2)^{2}(13.6\ eV) = - 54.4\ eV$
Therefore, to remove the second electron from the atom, the additional energy of 54.4 eV is required. Hence, total energy required to remove both the electrons $= 24.6 + 54.4 = 79.0\ eV$