Q. $v_{1}$ is the frequency of the series limit of Lyman series, $v_{2}$ is the frequency of the first line of Lyman series and $v_{3}$ is the frequency of the series limit of the Balmer series. Then

A) $v_{1} - v_{2} = v_{3}$
B) $v_{1} = v_{2} - v_{3}$
C) $\frac{1}{v_{2}} = \frac{1}{v_{1}} + \frac{1}{v_{3}}$
D) $\frac{1}{v_{1}} = \frac{1}{v_{2}} + \frac{1}{v_{3}}$
Explanation

(a) For Lyman series $v = RC\left\lbrack \frac{1}{1^{2}} - \frac{1}{n^{2}} \right\rbrack$
Where $n = 2,\ 3,\ 4,\ldots\ldots$
For the series limit of Lyman series $n = \infty$
$\therefore v_{1} = RC\left\lbrack \frac{1}{1^{2}} - \frac{1}{\infty^{2}} \right\rbrack = RC$ …(i)
For the first line of Lyman series, $n = 2$
$\therefore v_{2} = RC\left\lbrack \frac{1}{1^{2}} - \frac{1}{2^{2}} \right\rbrack = \frac{3}{4}RC$ …(ii)
For Balmer series $v = RC\left( \frac{1}{2^{2}} - \frac{1}{n^{2}} \right)$
Where $n = 3,\ 4,\ 5\ldots$
For the series limit of Balmer series $n = \infty$
$\therefore v_{3} = RC\left\lbrack \frac{1}{2^{2}} - \frac{1}{\infty^{2}} \right\rbrack = \frac{RC}{4}$ …(iii)
From equations (i), (ii) and (iii), we get
$v_{1} = v_{2} + v_{3} \Rightarrow v_{1} - v_{2} = v_{3}$

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.

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