(d)
Mol. wt.=$2 \times$ vapour density
$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ = 2 \times 45 = 90$
Empirical formula weight=12+2+16=30
$\therefore n = \frac{mol.wt}{empirical\ formula\ wt.}$
$\ \ \ \ \ \ \ = \frac{90}{30} = 3$
$\therefore$ Molecular formula of the compound
$= \left( CH_{2}O \right)_{3}$
$= C_{3}H_{6}O_{3}$